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  • Title: Absolute configuration of TPU-0043, a pentaene macrolide from Streptomyces sp.
    Author: Igarashi Y, In Y, Ishida T, Fujita T, Yamakawa T, Onaka H, Furumai T.
    Journal: J Antibiot (Tokyo); 2005 Aug; 58(8):523-5. PubMed ID: 16266125.
    Abstract:
    An antifungal pentaene macrolide TPU-0043 was isolated from Streptomyces sp. TP-A0625. The absolute configuration of TPU-0043 was determined to be 2R-(n-butyl)-16-methyl-3S,5S,7S,9R,11R,13R,15S,26S, 27R-nonahydroxyoctacosa-16,18,20,22,24-pentaenoic acid, 27-lactone, by X-ray crystallography of its 13-p-bromobenzenesulfonyl derivative.
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