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  • Title: A stereoselective cyclization to carbafuranose derivatives starting from 1,4-bis-epoxides.
    Author: Leung LM, Boydell AJ, Gibson V, Light ME, Linclau B.
    Journal: Org Lett; 2005 Nov 10; 7(23):5183-6. PubMed ID: 16268533.
    Abstract:
    [reactions: see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described.
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