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  • Title: Deconjugation of dehydroamino acids: stereoselective synthesis of racemic (E)-vinylglycines.
    Author: Alexander PA, Marsden SP, Muñoz Subtil DM, Reader JC.
    Journal: Org Lett; 2005 Nov 24; 7(24):5433-6. PubMed ID: 16288524.
    Abstract:
    [reaction: see text] A practical and general two-step synthesis of carbamate-protected (E)-vinylglycines from aliphatic aldehydes is reported. The key step involves the kinetic alpha-protonation of dianionic dienolates derived from dehydroamino acids.
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