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  • Title: A simple and efficient approach to 1,3-polyols: application to the synthesis of cryptocarya diacetate.
    Author: Kumar P, Gupta P, Naidu SV.
    Journal: Chemistry; 2006 Feb 01; 12(5):1397-402. PubMed ID: 16308881.
    Abstract:
    A highly enantio- and stereoselective synthetic strategy for both syn- and anti-1,3-polyols has been developed. The sequence involves iterative Jacobsen's hydrolytic kinetic resolution (HKR), diastereoselective iodine-induced electrophilic cyclization, and ring-closing metathesis (RCM). This protocol has subsequently been utilized for the synthesis of cryptocarya diacetate, a natural product with broad range of biological activity.
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