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  • Title: On the problem of field-gradient NMR measurements of intracrystalline diffusion in small crystallites--water in NaA zeolites as an example.
    Author: Gutsze A, Masierak W, Geil B, Kruk D, Pahlke H, Fujara F.
    Journal: Solid State Nucl Magn Reson; 2005 Sep; 28(2-4):244-9. PubMed ID: 16316747.
    Abstract:
    Necessary conditions for measuring intracrystalline diffusion in small crystal size systems via field-gradient NMR are discussed. As an illustrative case self-diffusion coefficients of water adsorbed in NaA zeolites (average crystal diameter about 1 microm) have been measured by 1H-NMR stimulated echoes in static magnetic field gradients of up to 180 T/m in the temperature range of 254-344 K. Obtaining intracrystalline diffusion coefficients necessitates a sufficiently high spatial resolution only provided by such large field gradients.
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