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  • Title: Photoelectron spectroscopy of S1 toluene: II. Intramolecular dynamics of selected vibrational levels in S1 toluene studied by nanosecond and picosecond time-resolved photoelectron spectroscopies.
    Author: Whiteside PT, King AK, Davies JA, Reid KL, Towrie M, Matousek P.
    Journal: J Chem Phys; 2005 Nov 22; 123(20):204317. PubMed ID: 16351266.
    Abstract:
    We present results which suggest that the photophysics of S(1) toluene is significantly more complicated than that of the related molecules p-fluorotoluene or p-difluorobenzene. We have measured a range of photoelectron spectra for a number of S(1) internal energies, on different time scales and at different temperatures, in an attempt to unravel the competing processes, but the final conclusion remains outstanding.
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