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  • Title: Gallium(III) complexes of methyl pyropheophorbide-a as synthetic models for investigation of diastereomerically controlled axial ligation towards chlorophylls.
    Author: Sasaki S, Mizoguchi T, Tamiaki H.
    Journal: Bioorg Med Chem Lett; 2006 Mar 01; 16(5):1168-71. PubMed ID: 16403627.
    Abstract:
    Gallium(III) chlorins possessing a series of axial ligands were synthesized as model compounds of natural chlorophylls. A pair of diastereomers arising from the fifth axial coordination onto the asymmetric chlorin pi-macrocycle could be discriminated in a solution by both (1)H- and (13)C NMR spectroscopies.
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