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  • Title: Structural and electronic behavior of unprecedented five-coordinate iron(III) and gallium(III) complexes with a new phenol-rich electroactive ligand.
    Author: Lanznaster M, Hratchian HP, Heeg MJ, Hryhorczuk LM, McGarvey BR, Schlegel HB, Verani CN.
    Journal: Inorg Chem; 2006 Feb 06; 45(3):955-7. PubMed ID: 16441098.
    Abstract:
    A new asymmetric pentadentate ligand was designed to impose low symmetry to trivalent ions. Five-coordinate Fe3+ and Ga3+ complexes were investigated by crystallographic, electrochemical, and electron paramagnetic resonance methods showing enhanced redox reversibility. Calculations were performed to account for the observed trends.
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