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  • Title: Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation.
    Author: Bandini M, Melloni A, Piccinelli F, Sinisi R, Tommasi S, Umani-Ronchi A.
    Journal: J Am Chem Soc; 2006 Feb 08; 128(5):1424-5. PubMed ID: 16448093.
    Abstract:
    A novel Pd-catalyzed intramolecular allylic alkylation of indoles allows THBCs and THGCs to be effectively synthesized in high yields and excellent enantiomeric excesses (ee up to 97%).
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