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  • Title: Oxidative and energetic efficiency of different electrochemical oxidation processes for chloroanilines abatement in aqueous medium.
    Author: Meinero S, Zerbinati O.
    Journal: Chemosphere; 2006 Jun; 64(3):386-92. PubMed ID: 16466769.
    Abstract:
    The oxidative efficiency and energy consumption, in the degradation of chloroanilines by anodic oxidation, indirect oxidation with electrogenerated hydrogen peroxide and electro-Fenton have been compared, using a laboratory system driven by a LabVIEW virtual controller. Solutions were oxidized in an undivided cell, where H(2)O(2) was generated electrochemically by reduction of atmospheric oxygen bubbled at a carbon cloth cathode. The electro-Fenton process showed the best degradation power, in terms of efficiency of removal and energy consumption. This process was applied to the purification of a solution obtained by washing a polluted soil. Under laboratory conditions, electro-Fenton removed 75% COD of this wastewater with a specific energy consumption of 0.3kWh per gram of COD, corresponding to 41.8kWhm(-3).
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