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  • Title: A concise total synthesis of (-)-cylindricine C through a stereoselective intramolecular aza-[3 + 3] annulation strategy.
    Author: Swidorski JJ, Wang J, Hsung RP.
    Journal: Org Lett; 2006 Feb 16; 8(4):777-80. PubMed ID: 16468765.
    Abstract:
    [reaction: see text] An enantioselective total synthesis of (-)-cylindricine C is described, featuring a diastereoselective intramolecular aza-[3 + 3] annulation strategy and an interesting halohydrin formation of the C4-5 olefin for construction of C4-ketone. This work provides a unique approach to this family of natural products.
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