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  • Title: Uranium(IV) complexes of calix[n]arenes (n = 4, 6 and 8).
    Author: Salmon L, Thuéry P, Ephritikhine M.
    Journal: Chem Commun (Camb); 2006 Feb 28; (8):856-8. PubMed ID: 16479290.
    Abstract:
    Reaction of UCl4 with calix[n]arenes (n = 4, 6 and 8) in THF or pyridine gave the mononuclear [UCl2(calix[4]arene--2H)(THF)2], bis-binuclear [U2Cl2(calix[6]arene--6H)(THF)3]2 and trinuclear [Hpy]6[U3Cl11(calix[8]arene--7H)] complexes, respectively, which are the first U(IV) complexes of O-unsubstituted calixarenes.
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