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  • Title: Racemic cis-methoxobis(2-methyl-3-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R2/2(7), R2/2(14) and R4/4(18) rings.
    Author: Kavitha SJ, Panchanatheswaran K, Low JN, Glidewell C.
    Journal: Acta Crystallogr C; 2006 Mar; 62(Pt 3):m116-8. PubMed ID: 16518035.
    Abstract:
    In the title compound, [V(CH3O)(C6H5O3)2O], the V-O bond lengths to the oxo and methoxo ligands are 1.593 (3) and 1.768 (3) A, respectively, at 120 K; the V-O bond lengths trans to these two ligands are 2.246 (3) and 2.116 (3) A. Molecules are linked by three C-H...O hydrogen bonds into complex ribbons containing three types of ring.
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