These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: A new kinetic model for the photopolymerization shrinkage-strain of dental composites and resin-monomers.
    Author: Atai M, Watts DC.
    Journal: Dent Mater; 2006 Aug; 22(8):785-91. PubMed ID: 16540163.
    Abstract:
    OBJECTIVES: The aim of the study was to develop a new kinetic model for the shrinkage-strain rates of dental resin composites. The effect of filler content on the shrinkage-strain kinetics and degree of conversion of dental composites was also investigated. METHODS: A resin matrix containing 65 wt.% Bis-GMA and 35 wt.% TEGDMA was prepared. 0.5 wt.% camphorquinone and 0.5 wt.% dimethyl aminoethyl methacrylate were dissolved in the resin as photo-initiator system. Silanized glass fillers were added in different percentages to the resin-monomers. The shrinkage-strain of the specimens photopolymerized at circa 550 mW/cm2 was measured using the bonded-disc technique at 23, 37 and 45 degrees C for the matrix monomers and 23 degrees C for the composites. Initial shrinkage-strain rates were obtained by numerical differentiation of shrinkage-strain data with respect to time. Degree-of-conversion of the composites containing different filler contents was measured using FTIR spectroscopy. RESULTS: A new kinetic model was developed for the shrinkage-strain rate using the autocatalytic model of Kamal [Kamal MR, Sourour S. Kinetic and thermal characterization of thermoset cure. Polym Eng Sci 1973;13(1):59-64], which is used to describe the reaction kinetics of thermoset resins. The model predictions were in good agreement with the experimental data. The results also showed a linear correlation between the shrinkage-strain (and shrinkage-strain rate) and filler-volume fraction. The filler fraction did not affect the degree-of-conversion of the composites. SIGNIFICANCE: The rate of polymerization, determined via the shrinkage, being invariant with filler-fraction, suggests that only a relatively high filler-surface area, as may be obtained with nano-fillers, will affect the network-forming kinetics of the resin matrix.
    [Abstract] [Full Text] [Related] [New Search]