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  • Title: Total synthesis of enantiopure (+)-gamma-lycorane using highly efficient Pd-catalyzed asymmetric allylic alkylation.
    Author: Chapsal BD, Ojima I.
    Journal: Org Lett; 2006 Mar 30; 8(7):1395-8. PubMed ID: 16562900.
    Abstract:
    [reaction: see text] A highly efficient short total synthesis of (+)-gamma-lycorane (>99% ee, 41% overall yield) was achieved by using the asymmetric allylic alkylation in the key step catalyzed by palladium complexes with novel chiral biphenol-based monodentate phosphoramidite ligands.
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