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  • Title: Supramolecular probe for bicarbonate exhibiting anomalous pyrene fluorescence in aqueous media.
    Author: Suzuki I, Ui M, Yamauchi A.
    Journal: J Am Chem Soc; 2006 Apr 12; 128(14):4498-9. PubMed ID: 16594647.
    Abstract:
    Highly selective HCO3- sensing is realized in a pH 8.6 aqueous solution on the basis of the HCO3--induced anomalous pyrene fluorescence of an association dimer that consists of pyrene-appended gamma-cyclodextrins having a triamine linker. The anomalous fluorescence that is produced by the HCO3--induced twisted conformation of the pyrene residues in the association dimer is insensitive to the presence of other anions.
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