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  • Title: Enantioselective total synthesis of bistramide A.
    Author: Crimmins MT, DeBaillie AC.
    Journal: J Am Chem Soc; 2006 Apr 19; 128(15):4936-7. PubMed ID: 16608311.
    Abstract:
    The enantioselective synthesis of bistramide A has been achieved with a longest linear sequence of 18 steps. The synthetic strategy involves the use of a distereoselective glycolate alkylation, an aldol addition of a chlorotitanium enolate of N-acylthiazolidinthione, and a Sharpless asymmetric epoxidation to synthesize the three key fragments.
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