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  • Title: Palladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.
    Author: Trost BM, Brennan MK.
    Journal: Org Lett; 2006 May 11; 8(10):2027-30. PubMed ID: 16671773.
    Abstract:
    [reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.
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