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  • Title: Rare Earth coordination polymers with zeolite topology constructed from 4-connected building units.
    Author: Guo X, Zhu G, Li Z, Chen Y, Li X, Qiu S.
    Journal: Inorg Chem; 2006 May 15; 45(10):4065-70. PubMed ID: 16676967.
    Abstract:
    A series of rare earth coordination polymers, M(BTC)(DMF)(DMSO) (M = Tb (1), Ho (2), Er (3), Yb (4), Y (5)), with zeolite ABW topology have been synthesized under mild conditions. They exhibit the same three-dimensional (3D) architecture and crystallize in monoclinic symmetry space group P2(1)/n. Their structures are built up from inorganic and organic 4-connected building units, whose vertex symbols are 4.4.6.6.6.8. The building units link to each other to generate approximate 5 x 8 angstroms2 channels along the [100] direction. The luminescent and magnetic properties of these compounds are investigated, and the results reveal that they could be anticipated to be potential antiferromagnetic and fluorescent materials.
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