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  • Title: Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality.
    Author: Branco LC, Gois PM, Lourenço NM, Kurteva VB, Afonso CA.
    Journal: Chem Commun (Camb); 2006 Jun 14; (22):2371-2. PubMed ID: 16733583.
    Abstract:
    New chiral ionic liquids can be prepared simply by combining the tetra-n-hexyl-dimethylguanidinium cation with readily available chiral anions and used as an asymmetric inducing agent as demonstrated for catalytic Rh(II) carbenoid C-H insertion and Sharpless dihydroxylation.
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