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  • Title: Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes.
    Author: Lu SF, Du DM, Xu J, Zhang SW.
    Journal: J Am Chem Soc; 2006 Jun 14; 128(23):7418-9. PubMed ID: 16756277.
    Abstract:
    The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).
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