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  • Title: Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes.
    Author: de Frémont P, Stevens ED, Fructos MR, Mar Díaz-Requejo M, Pérez PJ, Nolan SP.
    Journal: Chem Commun (Camb); 2006 May 21; (19):2045-7. PubMed ID: 16767270.
    Abstract:
    A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.
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