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  • Title: Double-responsive polymer brushes on the surface of colloid particles.
    Author: Zhang M, Liu L, Zhao H, Yang Y, Fu G, He B.
    Journal: J Colloid Interface Sci; 2006 Sep 01; 301(1):85-91. PubMed ID: 16780862.
    Abstract:
    Well-defined poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) brushes were synthesized on the surface of polystyrene latex particles by atom transfer radical polymerization (ATRP). It was found that the surface-initiated polymerization of DMAEMA catalyzed by CuCl/CuCl(2)/bpy was under good control in the solvent of acetone/water at ambient temperature (35 degrees C). High-density PDMAEMA brushes with low polydispersity (PDI 1.21) were obtained. TEM results demonstrate that the PDMAEMA-grafted particles have core-shell structure. Dynamic light scattering studies indicate that the particles with PDMAEMA brushes are both pH and temperature responsive.
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