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  • Title: Highly anti-selective catalytic aldol reactions of amides with aldehydes.
    Author: Saito S, Kobayashi S.
    Journal: J Am Chem Soc; 2006 Jul 12; 128(27):8704-5. PubMed ID: 16819844.
    Abstract:
    Barium phenoxide-catalyzed, highly anti-selective direct-type aldol reactions of amides with aldehydes have been developed. In the presence of a slight excess amount of an amide, the desired reactions proceeded smoothly under mild conditions, and a wide range of aromatic, heterocyclic, alpha,beta-unsaturated aldehydes were applicable to afford the desired adducts in high yields with high anti-selectivities. A catalytic, enantioselective reaction of an amide with an aldehyde using a chiral ligand is also described.
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