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  • Title: Interfacial molecular recognition of dissolved thymine by medium chain dialkyl melamine-type monolayers.
    Author: Vollhardt D, Liu F, Rudert R, He W.
    Journal: J Phys Chem B; 2005 Jun 02; 109(21):10849-57. PubMed ID: 16852320.
    Abstract:
    Systems consisting of an amphiphilic melamine-type monolayer and a pyrimidine derivative dissolved in the aqueous subphase are good candidates for the formation of interfacial supramolecular assemblies by molecular recognition of hydrogen-bond nonsurface-active species. In the present work, the change in the thermodynamic, phase, and structural properties as a result of molecular recognition of dissolved thymine by 2,4-di(n-undecylamino)-6-amino-1,3,5-triazine (2 C11H23-melamine) monolayers is studied. The combination of surface pressure studies with Brewster angle microscopy (BAM) imaging and grazing incidence X-ray diffraction (GIXD) measurements is optimal for the characterization of the change in structure and phase behavior at the interfacial recognition process. The molecular recognition of the nonsurface-active thymine dissolved in aqueous subphase changes drastically the characteristic features (surface pressure-area isotherms, morphology of the condensed phase domains) of the 2 C11H23-melamine monolayer. It is demonstrated that the kinetics of the recognition process affect largely the main characteristics (phase behavior, morphology of the condensed phase domains) of the interfacial system. The monolayers of 2 C11H23-melamine-thymine assemblies form dumbbell-shaped condensed phase domains not yet observed in other Langmuir monolayers so far. GIXD results show that the molecular recognition of thymine causes only quantitative changes in the two-dimensional lattice structure. Complementary hydrogen bonding of two thymine molecules by one 2 C11H23-melamine molecule is concluded from the chemical structure of both components. Additional information about the nature of the hydrogen bonding on the basis of supramolecular assemblies is obtained by using the quantum chemical PM3 approximation. Energy and lengths of the hydrogen bonds of the optimized thymine-2 C11H23-melamine-thymine structure are calculated.
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