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  • Title: 129Xe and 131Xe NMR of gas adsorption on single- and multi-walled carbon nanotubes.
    Author: Clewett CF, Pietrass T.
    Journal: J Phys Chem B; 2005 Sep 29; 109(38):17907-12. PubMed ID: 16853297.
    Abstract:
    129Xe and 131Xe nuclear magnetic resonance (NMR) spectroscopy was used to study the adsorption of xenon gas on as-produced single-walled and multi-walled carbon nanotubes. Overall, the adsorption was weak, with slightly stronger interaction between xenon and multi-walled nanotubes. Temperature-dependent spectra, relaxation times, line widths, and signal intensities provide evidence that xenon forms a multilayer bulk phase rather than a homogeneous surface coating. The estimated adsorption energy of 1.6 kJ/mol is significantly lower than 23 kJ/mol predicted for monolayer adsorption but is in keeping with the Xe-Xe attractive potential. Xenon preferentially adsorbs on metallic particles in single-walled tubes, while defects are the nucleation sites for the stronger adsorption on multi-walled tubes.
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