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  • Title: Wave patterns driven by chemomechanical instabilities in responsive gels.
    Author: Labrot V, De Kepper P, Boissonade J, Szalai I, Gauffre F.
    Journal: J Phys Chem B; 2005 Nov 24; 109(46):21476-80. PubMed ID: 16853785.
    Abstract:
    The first experimental evidence of a chemomechanical mechanism leading to morphogenetic instabilities is demonstrated experimentally. The system consists of a pH-responsive gel that swells at high pH and shrinks at low pH, and a bistable reaction system exhibiting an acid steady state (pH approximately 2) and an alkaline steady state (pH approximately 10). Within the gel, the steady state selection depends on the gel size. We show that in a constant and uniform nonequilibrium chemical environment, the responsive gel undergoes large amplitude dynamical deformations under the form of travelling contraction waves and complex spatio-temporal volume oscillations. These deformations are coupled to concentration patterns of protons. We present different sequences of dynamical behaviors observed under various controlled chemical conditions. A simple heuristic model is proposed to account for the observations. These experiments open a new route for pattern formation driven by chemical energy, in soft matter systems.
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