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  • Title: Scalable, catalytic asymmetric synthesis of syn, anti stereotriad building blocks for polypropionate antibiotics.
    Author: Parker KA, Cao H.
    Journal: Org Lett; 2006 Aug 03; 8(16):3541-4. PubMed ID: 16869655.
    Abstract:
    [reaction: see text] Asymmetric catalysis and chirality transfer by the 2,3-Wittig rearrangement were combined to provide a syn, anti stereotriad-containing olefinic alcohol in five steps from inexpensive starting materials. Development of this compound, a versatile intermediate for polypropionate synthesis, gave known building blocks for discodermolide.
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