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  • Title: Estimation of dielectric function of biotin-capped gold nanoparticles via signal enhancement on surface plasmon resonance.
    Author: Li X, Tamada K, Baba A, Knoll W, Hara M.
    Journal: J Phys Chem B; 2006 Aug 17; 110(32):15755-62. PubMed ID: 16898722.
    Abstract:
    Biotin-capped gold nanoparticles assembled on flat gold with volume fraction f are studied by surface plasmon resonance (SPR) spectroscopy and atomic force microscopy (AFM) in order to estimate the dielectric function of the gold nanoparticles based on the Maxwell-Garnett (MG) theory. The complex dielectric function (epsilon',epsilon'') of the spherical nanoparticles at three representative wavelengths in the vis-near-IR region, i.e., lambda = 543, 632.8, and 1152 nm, is estimated for a surface homogeneously covered with nanoparticles in order to discuss the wavelength dependence of the dielectric function. The SPR response of a surface covered with particles in 2D aggregates is also analyzed. The experimental SPR curve of the particle aggregates deviates from the theoretical predictions, suggesting dipole interactions between particles.
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