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  • Title: Synthesis of the ester side chains of some potently antileukemic harringtonia alkaloids from chiral citrates.
    Author: Ancliff RA, Russell AT, Sanderson AJ.
    Journal: Chem Commun (Camb); 2006 Aug 14; (30):3243-5. PubMed ID: 17028757.
    Abstract:
    The selective reduction of one of the three carboxyl groups of two chiral citric acid derivatives to the corresponding aldehydes, under Rosenmund conditions, are reported together with the application of these aldehydes to the syntheses of the ester side chains of some potently antileukemic Cephalotaxus alkaloids e.g. anhydroharringtonine.
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