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  • Title: Porous metal-organic framework with coordinatively unsaturated Mn(II) sites:sorption properties for various gases.
    Author: Moon HR, Kobayashi N, Suh MP.
    Journal: Inorg Chem; 2006 Oct 16; 45(21):8672-6. PubMed ID: 17029378.
    Abstract:
    A 3D porous metal-organic framework generating 1D channels, [Mn(NDC)(DEF)]n (1), has been prepared from the solvothermal reaction of Mn(II) and 2,6-naphthalenedicarboxylic acid (H2NDC) in diethylformamide (DEF). When DEF molecules coordinating Mn(II), which occupy the channels, are removed from 1 by heating the crystal of 1 at 250 degrees C under vacuum for 18 h, structural change occurs as evidenced by X-ray powder diffraction patterns. Desolvated solid [Mn(NDC)]n (2), which contains coordinatively unsaturated Mn(II) sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH4 gases and exhibits type I sorption behavior indicative of permanent microporosity.
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