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Title: Phosphate transfer from inositol pyrophosphates InsP5PP and InsP4(PP)2: a semi-empirical investigation. Author: Hand CE, Honek JF. Journal: Bioorg Med Chem Lett; 2007 Jan 01; 17(1):183-8. PubMed ID: 17045478. Abstract: A novel phosphate transfer process involving the non-enzymatic transfer of a phosphate group from inositol pyrophosphates to serine residues in proteins has been recently reported. Semi-empirical calculations at the PM3/SM5.2 level were undertaken to explore the effect of inositol pyrophosphate structure and overall charge on the thermodynamics of this phosphate transfer.[Abstract] [Full Text] [Related] [New Search]