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  • Title: Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes.
    Author: Shintani R, Duan WL, Park S, Hayashi T.
    Journal: Chem Commun (Camb); 2006 Sep 14; (34):3646-7. PubMed ID: 17047793.
    Abstract:
    A rhodium/binap complex has been found to effectively catalyze the isomerization of unactivated internal alkynes to the corresponding 1,3-dienes in the presence of an azomethine imine as the reaction promoter.
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