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  • Title: La@C72 having a non-IPR carbon cage.
    Author: Wakahara T, Nikawa H, Kikuchi T, Nakahodo T, Rahman GM, Tsuchiya T, Maeda Y, Akasaka T, Yoza K, Horn E, Yamamoto K, Mizorogi N, Slanina Z, Nagase S.
    Journal: J Am Chem Soc; 2006 Nov 08; 128(44):14228-9. PubMed ID: 17076475.
    Abstract:
    We show here that La@C72 has a non-IPR cage, unique electronic properties, and high reactivity by the spectroscopic and X-ray crystallographic analysis and the theoretical study. The isolation of La@C72 as a stable derivative might constitute an important stepping-stone on the way to isolation of these unknown metallofullerenes and open new material science of metallofullerenes.
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