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  • Title: Acidic iridium hydrides: implications for aerobic and Oppenauer oxidation of alcohols.
    Author: Gabrielsson A, van Leeuwen P, Kaim W.
    Journal: Chem Commun (Camb); 2006 Dec 21; (47):4926-7. PubMed ID: 17136249.
    Abstract:
    [Cp*Ir(H)(bpym)]+ and [Cp*Ir(H)(bpy)]+ are the first examples of iridium based catalysts for the aerobic oxidation of alcohols; the catalytic cycle proceeds via acidic hydrides. Deprotonation of the hydride leads to a highly oxygen sensitive Ir I species that regenerate the Ir III complexes upon oxidation with dioxygen.
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