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  • Title: Synthesis and hybridization studies on oligonucleotide-metal complex conjugates.
    Author: Hara K, Kitamura M, Inoue H.
    Journal: Nucleic Acids Symp Ser (Oxf); 2004; (48):217-8. PubMed ID: 17150556.
    Abstract:
    We synthesized a DNA oligomer with a terpyridine x Cu(II) complex-linked thymidine residue at phosphors the 5'-end. The attachment of the 5'-complex slightly enhanced the thermal stability of the DNA match-duplex. We also determined the thermal stabilities of the modified DNA duplexes and their unmodified counterparts, with a mismatched base-pair, to examine the effect of the complex on the stability.
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