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Title: Phase transfer catalyzed enantioselective Strecker reactions of alpha-amido sulfones with cyanohydrins. Author: Herrera RP, Sgarzani V, Bernardi L, Fini F, Pettersen D, Ricci A. Journal: J Org Chem; 2006 Dec 22; 71(26):9869-72. PubMed ID: 17168611. Abstract: A study into the use of a chiral phase-transfer catalyst in conjunction with acetone cyanohydrin to effect the enantioselective formation of alpha-amino nitriles from alpha-amido sulfones is described. This novel catalytic asymmetric Strecker reaction is analyzed with regard to the possible mechanistic basis.[Abstract] [Full Text] [Related] [New Search]