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  • Title: An efficient synthesis of epoxydiynes and a key fragment of neocarzinostatin chromophore.
    Author: Baker JR, Thominet O, Britton H, Caddick S.
    Journal: Org Lett; 2007 Jan 04; 9(1):45-8. PubMed ID: 17192081.
    Abstract:
    [reaction: see text] A key structural feature of the Neocarzinostatin chromophore is a reactive epoxydiyne. We present here a new method for the preparation of epoxydiynes by the addition of an allenyl zinc bromide to a propargylic ketone.
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