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  • Title: Synthesis of beta-lactam scaffolds for ditopic peptidomimetics.
    Author: Palomo C, Aizpurua JM, Balentova E, Jimenez A, Oyarbide J, Fratila RM, Miranda JI.
    Journal: Org Lett; 2007 Jan 04; 9(1):101-4. PubMed ID: 17192095.
    Abstract:
    [reaction: see text] Ring opening of alpha-substituted-alpha-methoxycarbonyl-N-nosylaziridines provides a practical access to enantiopure alpha,alpha'-disubstituted beta-lactam scaffolds, novel types of ditopic reverse turn surrogates. The procedure is general, short, and high yielding and starts from handy alpha-substituted serinates and alpha-amino acid derivatives.
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