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  • Title: Total synthesis of potential antitumor agent, (-)-dictyostatin.
    Author: Ramachandran PV, Srivastava A, Hazra D.
    Journal: Org Lett; 2007 Jan 04; 9(1):157-60. PubMed ID: 17192109.
    Abstract:
    [structure: see text] The potential antitumor agent (-)-dictyostatin has been synthesized utilizing Brown crotylboration to achieve eight of the eleven chiral centers. The yield for the 26-step longest sequence is approximately 4%. The C9-C10 coupling is achieved via a stereoselective vinylzincate addition.
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