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Title: Amine-promoted, organocatalytic aziridination of enones. Author: Armstrong A, Baxter CA, Lamont SG, Pape AR, Wincewicz R. Journal: Org Lett; 2007 Jan 18; 9(2):351-3. PubMed ID: 17217302. Abstract: A novel method is presented using N-N ylides (prepared by in situ amination of a tertiary amine) for the aziridination of a range of enone systems. The amine may be used sub-stoichiometrically, and promising levels of enantioselectivity are observed with quinine as promoter. [reaction: see text].[Abstract] [Full Text] [Related] [New Search]