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  • Title: Synthesis of the pyrrolidinone core of KSM-2690 B.
    Author: Donohoe TJ, Chiu JY, Thomas RE.
    Journal: Org Lett; 2007 Feb 01; 9(3):421-4. PubMed ID: 17249777.
    Abstract:
    [reaction: see text] The first synthesis of the pyrrolidinone core of the polyene beta-lactone antibiotic KSM-2690 B is described. An ammonia-free Birch reductive aldol reaction utilizing acetaldehyde is one of the key steps, together with a ruthenium-catalyzed alkene isomerization reaction.
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