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Title: Resolution of enantiomers in solution and determination of the chirality of extended metal atom chains. Author: Armstrong DW, Cotton FA, Petrovic AG, Polavarapu PL, Warnke MM. Journal: Inorg Chem; 2007 Mar 05; 46(5):1535-7. PubMed ID: 17269764. Abstract: The resolution of enantiomers of extended metal atom chains of the type Ni3[(C5H5N)2N]4Cl2 has been accomplished by chromatographic methods in solution, and the chirality was determined using vibrational circular dichroism, electronic circular dichroism, optical rotatory dispersion, and density functional theory calculations.[Abstract] [Full Text] [Related] [New Search]