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  • Title: An enantioselective Brønsted acid catalyzed enamine Mannich reaction.
    Author: Tillman AL, Dixon DJ.
    Journal: Org Biomol Chem; 2007 Feb 21; 5(4):606-9. PubMed ID: 17285167.
    Abstract:
    An enantioselective Brønsted acid catalyzed Mannich reaction between acetophenone derived enamines and N-Boc imines has been developed. Simple diol (S)-H(8)-BINOL has been identified as the optimal catalyst, to afford versatile beta-amino aryl ketones in good yield and enantiomeric excess.
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