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  • Title: Ether-directed, stereoselective aza-Claisen rearrangements: synthesis of the piperidine alkaloid, alpha-conhydrine.
    Author: Jamieson AG, Sutherland A.
    Journal: Org Lett; 2007 Apr 12; 9(8):1609-11. PubMed ID: 17371038.
    Abstract:
    [reaction: see text] A new approach for the stereoselective synthesis of the piperidine alkaloid (+)-alpha-conhydrine and its pyrrolidine derivative has been developed using a palladium(II)-catalyzed, MOM-ether-directed aza-Claisen rearrangement and ring-closing metathesis to effect the key steps.
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