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  • Title: Synthesis of nitrogen-containing compounds using chromium Fischer carbene complexes.
    Author: Kagoshima H, Fuchibe K, Akiyama T.
    Journal: Chem Rec; 2007; 7(2):104-14. PubMed ID: 17394197.
    Abstract:
    Synthetic utility of the Fischer-type carbene complexes of chromium for the preparation of nitrogen-containing compounds is demonstrated. Alkoxy carbene complexes reacted with imines to give (optically active) 3-pyrrolines and beta-methoxy allylic amine derivatives in good yields. The amino carbene complexes reacted with alpha,beta-unsaturated aldehydes to give substituted pyrroles in good yields.
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