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  • Title: Dual fluorescence of N-phenylanthranilic acid: Effect of solvents, pH and beta-cyclodextrin.
    Author: Rajendiran N, Balasubramanian T.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2007 Nov; 68(3):867-76. PubMed ID: 17433768.
    Abstract:
    Spectral characteristics of N-phenylanthranilic acid (NPAA) have been studied in different solvents, pH and beta-cyclodextrin (beta-CD) and compared with anthranilic acid (2-aminobenzoic acid, 2ABA). In all solvents a dual fluorescence is observed in NPAA, whereas 2ABA gives single emission. Combining the results observed in the absorption, fluorescence emission and fluorescence excitation spectra, it is found that strong intramolecular hydrogen bonding (IHB) interactions present in NPAA molecule. The inclusion complex of NPAA with beta-CD is analysed by UV-vis, fluorimetry, FT-IR, (1)H NMR, scanning electron microscope and AM 1 method. The above spectral studies show that NPAA forms a 1:1 inclusion complex with beta-CD and COOH group present in the beta-CD cavity. A mechanism is proposed to explain the inclusion process.
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