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  • Title: Structural study of the incorporation of heavy metals into solid phase formed during the oxidation of EDTA by permanganate at high pH.
    Author: Korshin GV, Chang HS, Frenkel AI, Ferguson JF.
    Journal: Environ Sci Technol; 2007 Apr 01; 41(7):2560-5. PubMed ID: 17438816.
    Abstract:
    Properties of solid phases formed during the oxidation of EDTA by permanganate in a high-pH, high-ionic strength solution, and the retention of Cu2+, Ni2+, and Zn2+ by them were examined. Morphologically, the solids were agglomerates of particles with sizes <100 nm. X-ray absorption spectroscopy (XAS) analysis indicated that these particles were birnessite. Its precipitation was accompanied by the removal of Zn2+ and Cu2+ released as a result of the breakdown of their complexes with EDTA. However, Ni2+ was not removed from the supernatant. Cu2+ was strongly bound by birnessite and exhibited little mobility in the pH range from 3 to 14. Zn2+ was more mobile, especially at pH > 12. XAS showed that Cu2+ binding sites were located within MnO6 octahedra-comprised sheets that constitute birnessite while Zn2+ was positioned between them.
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