These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Thermotropic liquid crystals based on extended 2,5-disubstituted-1,3,4-oxadiazoles: structure-property relationships, variable-temperature powder X-ray diffraction, and small-angle X-ray scattering studies.
    Author: Han J, Chui SS, Che CM.
    Journal: Chem Asian J; 2006 Dec 18; 1(6):814-25. PubMed ID: 17441124.
    Abstract:
    A class of extended 2,5-disubstituted-1,3,4-oxadiazoles R1-C6H4-{OC2N2}-C6H4-R2 (R1 = R2 = C10H21O 1 a, p-C10H21O-C6H4-C[triple bond]C 3 a, p-CH3O-C6H4-C[triple bond]C 3 b; R1 = C10H21O, R2 = CH3O 1 b, (CH3)2N 1 c; F 1 d; R1 = C10H21O-C6H4-C[triple bond]C, R2 = C10H21O 2 a, CH3O 2 b, (CH3)2N 2 c, F 2 d) were prepared, and their liquid-crystalline properties were examined. In CH2Cl2 solution, these compounds displayed a room-temperature emission with lambda(max) at 340-471 nm and quantum yields of 0.73-0.97. Compounds 1 d, 2 a-2 d, and 3 a exhibited various thermotropic mesophases (monotropic, enantiotropic nematic/smectic), which were examined by polarized-light optical microscopy and differential scanning calorimetry. Structure determination by a direct-space approach using simulated annealing or parallel tempering of the powder X-ray diffraction data revealed distinctive crystal-packing arrangements for mesogenic molecules 2 b and 3 a, leading to different nematic mesophase behavior, with 2 b being monotropic and 3 a enantiotropic in the narrow temperature range of 200-210 degrees C. The structural transitions associated with these crystalline solids and their mesophases were studied by variable-temperature X-ray diffractometry. Nondestructive phase transitions (crystal-to-crystal, crystal-to-mesophase, mesophase-to-liquid) were observed in the diffractograms of 1 b, 1 d, 2 b, 2 d, and 3 a measured at 25-200 degrees C. Powder X-ray diffraction and small-angle X-ray scattering data revealed that the structure of the annealed solid residue 2 b reverted to its original crystal/molecular packing when the isotropic liquid was cooled to room temperature. Structure-property relationships within these mesomorphic solids are discussed in the context of their molecular structures and intermolecular interactions.
    [Abstract] [Full Text] [Related] [New Search]