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  • Title: Revisiting the morphology development of solvent-swollen composite polymer particles at thermodynamic equilibrium.
    Author: Saito N, Kagari Y, Okubo M.
    Journal: Langmuir; 2007 May 22; 23(11):5914-9. PubMed ID: 17441739.
    Abstract:
    Morphology of polystyrene (PS)/poly(methyl methacrylate) (PMMA)/toluene droplets, in which phase separation proceeds, dispersed in SDS aqueous solution was examined. It changed from ex-centered PS-core/PMMA-shell to hemisphere with increasing SDS concentration. At low polymer weight fraction (wp), PS and PMMA phases contained non-negligible amount of PMMA and PS, respectively. The small amount of PS and PMMA in PMMA and PS phases, respectively, affected significantly the interfacial tension between polymer/toluene and aqueous solutions. Interfacial tension between PS and PMMA phases at low wp was measured by the spinning drop method, showing a quite low value ( approximately 10-2 mN/m). Predicted morphology obtained from calculation of minimum total interfacial free energy of the droplets using the interfacial tensions agreed well with the experimental observation.
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